cerium(iv) as ceric triethylammonium nitrate: an efficient catalyst for protection and deprotection of alcohols with dihydropyran

نویسندگان

nasser iranpoor

peyman slalehi

چکیده

catalytic amount of ce(iv) as ceric triethylammonium nitrate (ctean) in dichloromethane or acetone can bring about an efficient tetrahydropyranylation of different types of alcohols to afford the corrsesponding tetrahydropyranyl ethers in high yields. deportection of tetrahydropyranyl ethers can also be achieved efficiently in the presence of this catalyst in methanol.

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منابع مشابه

Cerium(IV) as Ceric Triethylammonium Nitrate: An Efficient Catalyst for Protection and Deprotection of Alcohols with Dihydropyran

Catalytic amount of Ce(IV) as ceric triethylammonium nitrate (CTEAN) in dichloromethane or acetone can bring about an efficient tetrahydropyranylation of different types of alcohols to afford the corrsesponding tetrahydropyranyl ethers in high yields. Deportection of tetrahydropyranyl ethers can also be achieved efficiently in the presence of this catalyst in methanol.

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Ammonium Decatungstocerate(IV): An Efficient Catalyst for the Protection and Deprotection of Tetrahydropyranyl Ethers

In multi-step organic syntheses, the protection and deprotection of tetrahydropyranyl (THP) ethers is one of the most frequently used methods. Over the years, different methods have been used from various catalytic systems for the protection of hydroxyl groups as THP ethers and their deprotection. Herein we have reported that various alcohols and phenols have been efficiently converted to the c...

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ammonium decatungstocerate(iv): an efficient catalyst for the protection and deprotection of tetrahydropyranyl ethers

in multi-step organic syntheses, the protection and deprotection of tetrahydropyranyl (thp) ethers is one of the most frequently used methods. over the years, different methods have been used from various catalytic systems for the protection of hydroxyl groups as thp ethers and their deprotection. herein we have reported that various alcohols and phenols have been efficiently converted to the c...

متن کامل

ammonium decatungstocerate(iv): an efficient catalyst for the protection and deprotection of tetrahydropyranyl ethers

in multi-step organic syntheses, the protection and deprotection of tetrahydropyranyl (thp) ethers is one of the most frequently used methods. over the years, different methods have been used from various catalytic systems for the protection of hydroxyl groups as thp ethers and their deprotection. herein we have reported that various alcohols and phenols have been efficiently converted to the c...

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Melamine trisulfonic acid: A new, efficient and reusable catalyst for the protection of alcohols, phenols, aldehydes and amines

Tetrahydropyranylation of alcohols and phenols, acetylation of aldehydes and N-Boc protection of amines are efficiently catalyzed by melamine trisulfonic acid (MTSA). All reactions were performed at room temperature in good to high yields.

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عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)

ناشر: iranian institute of research and development in chemical industries (irdci)-acecr

ISSN 1021-9986

دوره 15

شماره 1 1996

میزبانی شده توسط پلتفرم ابری doprax.com

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